Electrochemical Parameter Identification for Lithium-ion Battery Sources in Self-Sustained Transportation Energy Systems

Lithium-ion battery (LIB) sources have played an essential role in self-sustained transportation energy systems and have been widely deployed in the last few years. To realize reliable battery maintenance, identifying its electrochemical parameters is necessary. However, the battery model contains many parameters while the measurable states are only the current and voltage, inducing the identification inherently an ill-conditioned problem. A parameter identification approach is proposed, including the experiment, model, and algorithm. Electrochemical parameters are first grouped manually based on the physical properties and assigned to two sequenced tests for identification. The two tests named the quasi-static test and the dynamic test, are compressed on time for practical implementation. Proper optimization models and a sensitivity-oriented stepwise (SSO) optimization algorithm are developed to search for the optimal parameters efficiently. Typically, the Sobol method is applied to conduct the sensitivity analysis. Based on the sensitivity indexes, the SSO algorithm can decouple the mixed impacts of different parameters during the identification. For validation, numerical experiments on a typical NCM811 battery at different life stages are conducted. The proposed approach saves about half the time finding the proper parameter value. The identification accuracy of crucial parameters related to battery degradation can exceed 95\%. Case study results indicate that the identified parameters can not only improve the accuracy of the battery model but also be used as the indicator of the battery SOH.