This paper considers a wireless network with a base station (BS) conducting timely transmission to two clients in a slotted manner via hybrid non-orthogonal multiple access (NOMA)/orthogonal multiple access (OMA). Specifically, the BS is able to adaptively switch between NOMA and OMA for the downlink transmission to minimize the information freshness, characterized by Age of Information (AoI), of the network... If the BS chooses OMA, it can only serve one client within a time slot and should decide which client to serve; if the BS chooses NOMA, it can serve both clients simultaneously and should decide the power allocated to each client. To minimize the weighted sum of expected AoI of the network, we formulate a Markov Decision Process (MDP) problem and develop an optimal policy for the BS to decide whether to use NOMA or OMA for each downlink transmission based on the instantaneous AoI of both clients. We prove the existence of optimal stationary and deterministic policy, and perform action elimination to reduce the action space for lower computation complexity. The optimal policy is shown to have a switching-type property with obvious decision switching boundaries. A suboptimal policy with lower computation complexity is also devised, which can achieve near-optimal performance according to our simulation results. The performance of different policies under different system settings is compared and analyzed in numerical results to provide useful insights for practical system designs. (read more)